One-step templated synthesis of chiral organometallic salicyloxazoline complexes
نویسندگان
چکیده
منابع مشابه
One-step multicomponent synthesis of chiral oxazolinyl-zinc complexes
BACKGROUND Typically, oxazolinyl metal complexes are synthesized in two steps, where the free ligand is prepared by the condensation reaction between a functionalized nitrile and an amino alcohol in the presence of a Lewis or Brønsted acid catalyst, followed by a further reaction with metal salts to obtain the corresponding metal complexes. Very often, the yield afforded by the two-step procedu...
متن کاملErratum to: One-step multicomponent synthesis of chiral oxazolinyl-zinc complexes
© The Author(s) 2017. This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if c...
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The addition of an aryllithium reagent to a secondary boronic ester leads to an intermediate boron-ate complex that behaves as a chiral nucleophile, reacting with a broad range of electrophiles with inversion of stereochemistry. Depending on the electrophile, the C-B bond can be converted into C-I, C-Br, C-Cl, C-N, C-O, and C-C, all with very high levels of stereocontrol. This discovery now add...
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ژورنال
عنوان ژورنال: BMC Chemistry
سال: 2019
ISSN: 2661-801X
DOI: 10.1186/s13065-019-0565-z